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Safety Data Sheet <br />Material Name: Copper Sulfate Pentabydrate ID: Cl-121A <br />* **Section 14-Transportation Information Vessel * * * <br />Amendment 37-14 Inte rnationa l Maritime Dangerous Goods (JMDG) Code <br />for shipments via marine vessel transport, the following classification information applies. <br />v <br />UNINA #: UN 3077 <br />Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOL ID , N.O.S. (Cupri c s ul fate) <br />Hazard Class: 9 <br />Pacl<ing Group: Jll <br />Special Provisions:274,335,966,967 <br />Limited Quantities 5 kg <br />Excepted Quantities: E 1 <br />Packing Instructions: P002/LP02 <br />Provisions: PP I 2 <br />IBC Instructions 1B C08 <br />lBC Provisions: B2 <br />EmS: F-A, S-F <br />Stowage and: Handling Category A., SW23 <br />Segregation: None <br />Marine Pollutant: This material is considered a marine pollutant by the lMO a nd s hipm e nts of the material must carry the new marking <br />Refer to IMO Amendment 36-12 Chapter 2.9 and 2.10. <br />¢ L;m;tod Qu•nti ty Sh;pm'""' Sh;pm'"" n"d not bo m"kod whh tho P•opoc Sh;p p;.g Namo oftho '""""·bot sha ll <br />be marked with a diamond. The top and bottom portions of th e sq uare -on-po in t must be black and the center white o r of a su it able <br />contrasting background. The mark mu st be at leas! 2 mm. Each side must have a minimum dimension of I 00 mm. Small packages which <br />cannot reasonably accommodate a 100 mm square -on-point mark may be marked with a square-on-point mark with a minimum side <br />dimension of 50 mm. The total weigh t of each outer packaging cannot exceed 30 kg (66 pounds). A lao requires an IMDG Dangerous <br />Cargo Declaration. <br />Excepted Quantities: The maximum quantity of th is material per inne r rec eptacle is limited to 30 g per receptacle and the aggregate <br />quantity of thi s material per completed package does not exceed I OOOg. The inner receptacles must be securely packed in an int ermediate <br />packaging with cushioning material to prevent movement in the inner receptacles and packed in a strong o uter box with a gross mass not t o <br />exceed 29kg. The completed package must meet a drop test. The requirements are found in 3.5.3.1. T he rackage must not be opened or <br />otherwise a ltered until it is no longer in commerce. For air transportation no sh i pp ing paper is required. The package must be legibly <br />marked with th e following marking: <br />,,,,,,,,,,, <br />~ e ~ ; I I I <br />I I <br />' I I I <br />' ' 1,,,,,,,,,, ... ~ <br />,NOTE: The ··· must be replaced by the primary hazard dass, or when assigned. the division or each or the hazardous materials contained In the package. <br />The ··~ must be replaced by the name of the shipper or consi gnee If not shown elsewhere on the package. The symbol sha ll be not less than 100 mm x 100 mm and must be <br />durable and clearly visible. <br />Iss ue Date: 09/09/98 13:25:58 CLW Page 12 ofl4 Revi sion Date: 01/14/2 015 13:00 CST <br />6.3.A. - Page 147