AgdaPkt 2016-02-22 Closed and Interview and Joint SA PFA

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Safety Data Sheet Material Name: Copper Sulfate Pentahydrate ID: Cl-121A interval (REI) of 48 hours. PPE required for early entry to treated areas that is permitted under the Worker Protection Standard and that involves contact with anything that has been treated, such as plants, soil or water, is " Coveralls, waterproof gloves, shoes, plus socks and protective eyewear. Labeling Information for Pesticide Use of Product (continued): GENERAL USE INSTRUCTIONS: Water hardness, temperature of the water, the type and amount of vegetation to be controlled and the amount of water now, are to be considered in using Copper Sulfate to control algae. Begin treatment soon alter plant gro>vth has started. I f treatment is de layed until a large amount of a lgae is present. larger quantit ies of Copper Sulfate will required. Algal growth is dif1icult to control with Copper Su lfate when water temperatures ar·e low or when water is hard. Larger quantities of Copper Sulfute will be required to kill and control a lgae in water which is flowing than in a body of s tagnant water. If possible, cut1ail the flow of water before treatment and hold d01mant unti l approximately three days after treatment or until the algae have begun to die. When preparing a Copper Sui fute solution in water, the mixing container should be made of plastic or glass, or a painted , enameled, or copper-lined m etal container. It is usL1ally best to treat a lgae on a sunny day when the heavy mats of filamentous algae are most likely to be floating o n the surface, allowing the so lution to be sprayed directly on th e algae. If there is some doubt about the concentration to apply, it is generall y best to start with a lower concentration and to increase this concentration unt.il the algae are killed. ENDANGERE D SPECIES RESTRJCTION: It is a violation of Federal Law to use any pesticide in a manner that results in the death of an endangered species or adverse modification to their habitat. The use of this product may pose a hazard to certain Federally Des ignated spec ies known to occur in specific areas. Contact the EPA for infonnation on these areas. Obtain a copy ofthe EPA Bulletin specific to you r area. This bull et in identifies areas within specific State counties where the use of thi s pesticide is prohibited, unless specified otherwise. The EPA Bull etin is available from ei ther your County Agricultural Extension Agent. the E ndangered Species Specialist in your State Wildlife Agency Headquarters, or th e appropriate Regional Office of the U.S. Fish and Wi ldlife Service. Tf-nS BULLETIN MUST BE REVIEWED PRJOR TO PESTICIDE USE. EPA REG. NO. 56576-EPA EST . NO . 52117-MX-001 Other rnformation Chern One Ltd. ("Chern One") s ha ll not be responsible for the use of any information, product, method, or appa ratus herein presented ("Information"), and you must make your own determination as to its s uitability and comp leteness for your own use. for the protection of the environment, and for health and safety purposes. You assume the entire risk of rel y ing on this Information. In no event shall Chern One be responsible for damages of a ny nature whatsoever resulting fi·om the use of this product or products, or reliance upon this In format ion. By prov iding th is Info rm ation , Chem One neither can nor intends to control the method or manner by which you use, handle , store, or transport Chern One products. If any materials are me ntioned that are not Chern One produ cts, appropriate industrial hygiene and other safety precautions recomm e nded by their manufacturers should be observed. Chern One makes no representations or warranties, either express or implied of merchantability, fitn ess tor a particular purpose or o f any other nature regarding this information. and nothing herein waives any of Chern One's conditions of sale. This information could in clude techn ical inaccuracies or typographical errors. Chem One may make improvements and/o r changes in the product (s) and/o r the program (s) described in this infcnmation at any time. If you have any questions, p lease contact us at Tel. 713-896-9966 or E-ma il us at Snfetv@ c hemone.com, Key/Legend EPA -E nvironmental Protection Agency; TSCA -Toxic Substance Control Act; ACGIH =American Conference of Governmental Industrial Hygienists; TARC =International Age nc y for Researc h on Cancer; N IOSH = Nationa llnstitute for Occupational Safety and Hea lth ; NTP =National Tox icology Program ; OSHA= Occu pational Safety and Health Administration Contact: Sue Palmer-Koleman , PhD Contact Phone: (7I3) 896-9966 Revision log 07/24/00 4:24PM SEP Changed co mpany name, Sect I and I6. from Corporation to Ltd. 07/27/00 2:49PM SEP Added ''fine 200, rcc IV, Very Jligh Purity" to synonyms, Section l 08/23/00 3:15PM SEP Added "Copper Sulfate C1ystals" to synonyms, Section I 05/31/0J 9:3I AM llDF Checked exposure limits; made changes t o Sect 9; overall rev iew, add SARA 311 /312 Haz Ratings . 06/0 I /01 7:28AM HDF Added text to lab e l infonnation from EPA Approved Label 07/24/01 4:31 AM CLJ Add Shipments by Air intormation to Section 14, Changed contact to Sue, non-800 Chemtrec Num . 09/18/01 1 I :34 AM SEP Added Domestic Transportation Exception , Sect l4 L0/05/01 3:30PM SEP Deleted Alternate Shipping Name, Sect 14 02/15/02 11 :0 I AM: HDF Revision of SARA Chronic I Jaza.rd Rating lo "Yes". 2/2 1/02 4:21 PM HDF Added more intormation on Marine Pollutant Markings and Limited Quantity Shipments 9/16/03: 3:45PM HDF Addidon of chronic hea lth hazard information. Addition of inhalation hazard information, Section 3. Section 4. expansion of information on Information tor Physic ians. U p-grade d Section I 0 Reactivity Information. Up-dated DFG MAK exposure limits. Up -Dated entire Section I4 Transpmtatiori Information to in clude lATA , IMO and current Canadian transport in formation. Iss ue Date : 09/0919 8 13:25:58 CLW Page 15 ofl4 Re vis ion Date: 01/14/2 015 13:00 CST 6.3.A. - Page 150