AgdaPkt 2016-02-22 Closed and Interview and Joint SA PFA

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Safety Data Sheet Material Name: Copper Sulfate Pentahydrate ID: Cl-121A * * * Section 6-Accidental Release Measures Continued * * * Evacuation Procedures Evacuate th e a rea promptl y and keep upwind of the spilled materia l. Isolate th e spill a rea to preve nt people fi·om en te rin g. Keep materials which can burn away 1i·om spi li ed materi a l. In case of large spills . follow a ll faci lity emergency response procedu res. Special Procedures Remove soiled clothing and launder before reuse. Avoid a ll s kin contact with th e spill ed material. H ave emergency equipment rea dil y available. * * * Section 7 -Handlino and Storage * * * Handling Procedures It is a violation ofFed eral Law to use this prod uct i n a manner in consistent with its labeling, when used as a pesticide. Do not breath e dust. Avo id all contact wi th skin a nd eyes. Use this product on ly wi th adequate ventil ation. Wash thoroughly after hand lin g . Storage Procedures Keep in original container in locked storage area. Keep container tightly c losed when not in use. Store containers in a cool , d ry locati o n, away from direct s unlig ht, sources o f intense heat, or where fi·eezin g is possible. Material should be s tored in secondary containers or in a diked area, as appropriate. Store containers away trom incompatible c hemica ls (see Section I 0, Stab ilit y and R eactiv ity). Storage areas s houJd be made of fire-resistant mate riaJ s . Post warning and "NO SMOKlNG" s igns in s torage and use areas, as appropriate. Use corrosio n-resistant stru ctural materials, lighting. and ventilation systems i n the storage area. Floors should be sealed to prevent abso rpti on of thi s ma teria l. Have appropria te extingu ishin g equipm ent i11 th e stora ge area (i.e ., sprinkl e r system , portable fire extinguishe rs). E mp ty conta iners may con ta in residual pa1i ic ul ates; th e refore , empty containers s ho uld be handled with care. Do not cut, g1iod, weld , o r drill near thi s container. Never s to re food , feed , or drinking water in containers th a t he ld this product. Keep this materia l away from food , drink a nd anim al fee d. In spect a ll incomin g containers betore storage, to ensure contain e rs are properly labeled and not damaged . D o not store thi s material in open or unlabeled containers. Limit quantity of mate rial stored. Store in s uitable containe rs th a t are corros ion .resistant. * * * Section 8 -Expos ure Controls I Personal Protection * ·ic * Exposure Guidelines A: General Product Information foll ow the applicabl e exposu re limits. B: ComJ>Onent Exposure Limits The exposure limits given are for Copper & Inorganic Compounds, as C u and mists, as Cu. ACGT£-1: OSHA: N IOSH: I mg/m 3 TWA (dus ts & mists) 0.2 mg/m 3 TWA (fi.1me) I mg/m 3 TWA (dusts & mi sts) 0.1 mg/m3 T WA (.fu me) l mg/m3 TWA(dus ts&mi sts) 0 .1 mg/m 3 TWA (fum e) (7440-50-8), Copper fume as Cu or Copper dusts DFG MAK.s I mg/m3 TWA Peak, 2•MAK 15 minutes, average valu e, 1-hr in terva l (copper a nd ino rgani c copper compounds) 0 .1 mg/m3 TWA Peak, 2•MAK15 minutes, average value, 1-hr in terval (fume) C omponent Related Regulatory Information T hi s product may be regul ated, have exposure limits or othe r information id e ntifi ed as th e following: Copper (7440-50-8) and in o rga nic co mp o und s, as Cu. Coppe r (7440-50-8) dusts and mis ts, as Cu a nd Co pper fum e , C u. Engineering Conh·ols Use mechanical ventilati o n such as dilution and local exhau st. Use a corrosion -resistant ventilation system and exha ust directl y t o the outside. Suppl y ample air replace ment. Provide dust co ll ec tors w ith explosio n vents. Jssue Date: 09/09/98 13:25:58 CLW Page 4of 14 Rev is ion Date: OJ/14/2015 13 :00 CST 6.3.A. - Page 139